Film Preservation Handbook

Conservation Treatments

Blocked decomposed film

As a cellulose acetate film decomposes the acids formed create an environment in the film base polymer that causes the additives such as triphenyl phosphate (TPP) to migrate to the surface of the film base. Some of the additives will move through the emulsion, creating small rupture marks. In extreme cases these will cause large holes to appear in the emulsion. Examples of these, the black holes in the upper left and right corners, are shown in Fig 12.16.

While the acid levels are building the gelatin is also being affected, the decrease in pH creating a positively charged surface. The TPP is attracted to positive charges and will bond to the charges on the surface of the gelatin, emulsion and backing layer. TPP will also form intermolecular bonds that eventually form a solid layer that is bonded to each of the gelatin layers. This turns the film into a solid blocked mass.

^{Fig 12.14 Decomposed blocked film with typical crystal growth on the surface of the reel}

^{Fig 12.16 Frame with crystal growth affecting the image}

^{Fig 12.15 TPP's role in blocking decomposed film}

Unblocking decomposed film
Since it is the TPP that is creating the adhesion, to unblock the film a solvent that dissolves TPP is required. Selection of a suitable solvent is critical to prevent minimal leaching of the plasticisers that still remain in the film base.

Ethanol is a very effective solvent but will also readily leach any remaining plasticisers from the base. Ethanol also reacts with the acid (acetic and nitric¹) with one of the by-products being water. The water produced will substantially soften the emulsion gelatin. To reduce the amount of water produced an approximately 2% mixture of ethanol and 3M HFE 71-DA is used, the exact concentration needed is established on a case-by-case basis.

^{Fig 12.17 Applying unblocking solution to a film}

To apply the solvent a small syringe is used to drop a small amount of solution at the interface between the layers of film as it is unwound.

The procedure is slow and painstaking and requires a deal of care to prevent damage to the emulsion which becomes very soft. Fortunately the dissolution of TPP is a fast reaction.

¹ WARNING ethanol reacts exothermically with nitric acid and generates toxic nitrogen oxides. For this reason ethanol should not be used for unblocking nitrate film.

^{HIGH HUMIDITY & TIGHT WIND}